A Linear Trinuclear Cobalt(II) Complex with Acetate Bridging Ligang:Hexakisacetatodiphenanthrolinetricobalt(II)
نویسندگان
چکیده
منابع مشابه
Trinuclear Mn(II) complex with paramagnetic bridging 1,2,3-dithiazolyl ligands.
The first metal coordination complex of a radical ligand based on the 1,2,3-dithiazolyl heterocycle is reported. 6,7-Dimethyl-1,4-dioxo-naphtho[2,3-d][1,2,3]dithiazolyl acts as a bridging ligand in the volatile trinuclear Mn(hfac)(2)-Rad-Mn(hfac)(2)-Rad-Mn(hfac)(2) complex (hfac = 1,1,1,5,5,5-hexafluoroacetylacetonato-). The Mn(II) and radical ligand spins are coupled anti-ferromagnetically (AF...
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[Ni3(C2H3 0 2 )2(CH3 0 H)2L2] [L = l,3-bis(5-chlorosalicylideneamino)propan-2-ol dianion, (C2H3 0 2 )_ = acetate, (CH3OH) = methanol] was synthesized and its crystal structure was determined. It crystallizes in the monoclinic spaceeroup P2i /n with a = 12.694(2), b = 13.281 (4), c = 15.420(3) Ä, ß = 111.25(2)°, V = 2422.9(9) A ? ,Z = 2 . The molecule is a “linear” trinuclear complex with nearly...
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ژورنال
عنوان ژورنال: Journal of the Korean Chemical Society
سال: 2003
ISSN: 1017-2548
DOI: 10.5012/jkcs.2003.47.6.667